Possible Clues:

• Harbour staff reported tug in case that's needed on voyage?
• "Bromance" or "Bennifer," e.g
• Case of fortified wine chap tasted initially with water in Paris
• A term invented by Lewis Carroll for words such as brunch, chortle or smog
• 'Frenemy' or 'frankenfood'
• Term for the other longest answers in the puzzle (and 92 Down)
• Left chap kind of cross about English classification of the across solutions?
• Compound word
• Word like ''smog''
• Dock on isle and cross round base in carrier