Possible Clues:

• -- Paulo
• . . . Paulo, Brazilian city
• ___ Tomé and Príncipe (equatorial land)
• Neptune moon discovered in '02
• ___ Tiago (one of the Cape Verde islands)
• Start for "Paulo" or "Luis"
• ___ Tomé and Príncipe
• It starts the Western Hemisphere's most populous city
• Saint, in Rio
• ___ João de Meriti, Brazil